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रसायन विज्ञान >> इनआर्गेनिक केमिस्ट्री इनआर्गेनिक केमिस्ट्रीडॉ. रश्मि जिन्दल
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उत्तर प्रदेश के विभिन्न विश्वविद्यालयों के केमिस्ट्री बी.एस-सी. तृतीय वर्ष के प्रथम प्रश्नपत्र हेतु स्वीकृत एकीकृत पाठ्यक्रम पर आधारित अंग्रेजी माध्यम में
SYLLABUS
B.Sc. Part III, Paper I
Inorganic Chemistry
Unit - I
i. Metal-ligand bonding in Transition Metal Complexes
Limitations of valence bond theory, an elementary idea of crystal field theory, crystal field splitting in octahedral, tetrahedral and square planner complexes factors affecting the crystal-field parameters.
ii. Thermodynamic and Kinetic Aspects of Metal Complexes
A brief outline of thermodynamics stability of metal complexes and factors affecting the stability, stability constants of complexes and their determination, substitution reactions of square planar complexes.
Unit - II
iii. Magnetic Properties of Transition Metal Complexes
Types of magnetic behaviour, methods of determining magnetic susceptibility, spin-only formula, L-S coupling, correlation of Ms and Mel values, orbital contribution to magnetic moments, application of magnetic moment data for 3d-metal complexes.
iv. Electronic Spectra of Transition Metal Complexes
Types of electronic transitions, selection rules for d-d transitions, spectroscopic ground states, spectrochemical series, Orgel-energy level diagram ford' and do states, discussion of the electronic spectra of [Ti(H20)6]3+ complex ion.
Unit - III
v. Organometallic Chemistry
Definition, nomenclature and classification of organometallic compounds, Preparation, properties, bonding and applications of alkyls and aryls of Li, AI, Hg, tin and titanum. Metal carbonyls: 18 electron rule, preparation, structure and nature of bonding in the mononuclear carbonyls.
vi. Silicones and Phosphazenes
Silicones and phosphazenes as examples of inorganic polymers, nature of bonding in triphosphazenes.
Unit - IV
vii. Hard and Soft Acids and Bases (HSAB)
Classification of acids and bases as hard and soft, Pearson's HSAB concept, acid-base strength and hardness and softness, Symbiosis, theoretical basis of hardness and softness, electronegativity and hardness and softness.
viii. Bioinorganic Chemistry
Essential and trace elements in biological processes, metalloporphyrins with special reference to haemoglobin and myoglobin, Biological role of alkaline earth metal ions with special reference to Cat.
CONTENTS
1. Metal-Ligand Bonding in Transition Metal Complexes ... 1–36
2. Thermodynamic and Kinetic Aspects of Metal Complexes ... 37-58
3. Magnetic Properties of Transition Metal Complexes ... 59–86
4. Electronic Spectra of Transition Metal Complexes ... 87–106
5. Organometallic Chemistry ... 107-155
6. Silicones and Phosphazenes ... 156–183
7. Hard and Soft Acids and Bases ... 184–203
8. Bioinorganic Chemistry ... 204–224
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